Phosphane–ene chemistry: the reactivity of air-stable primary phosphines and their compatibility with the thiol

Phosphane–ene chemistry: the reactivity of air-stable primary phosphines and their compatibility with the thiol–ene reaction

Published:2015 Issue:35 Volume:44 Page:15664-15670
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Guterman Ryan¹²³⁴,Gillies Elizabeth R.¹²³⁴⁵,Ragogna Paul J.¹²³⁴

Affiliation:

1. The University of Western Ontario

2. Department of Chemistry and the Centre for Advanced Materials and Biomaterials Research (CAMBR)

3. London

4. Canada

5. Department of Chemical and Biochemical Engineering

Abstract

Air-sensitive and air-stable primary phosphines (RPH₂) were compared for their ability to undergo photoinitiated phosphane–ene chemistry with 1-hexene.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02364E

Reference34 articles.

1. G. Odian , Principles of Polymerization, John Wiley & Sons, Inc., New York, 4th edn, 2004

2. J. E. Mark , H. R.Allcock and R.Wester, Inorganic Polymers, Oxford University Press, 2005

3. Thiol-Ene Click Chemistry

4. Toward an enhanced understanding and implementation of photopolymerization reactions

5. Phospha-organic chemistry: from molecules to polymers

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