Halide encapsulation by dicarboxylate oxido-vanadium cage complexes
Author:
Affiliation:
1. Departamento de Química Inorgánica
2. Universidad de Sevilla
3. 41071 Sevilla
4. Spain
5. Instituto de Investigaciones Químicas
6. CSIC – Universidad de Sevilla
7. 41092 Sevilla
8. Departamento de Química Física
Abstract
The nature of the encapsulated halide governs the shape and dimensions of cages in [Bu4N]2[V8O16(oda)4⊂2Cl] and [Bu4N][V4O8(glut)2⊂F] complexes, by the template effect.
Funder
Ministerio de Economía y Competitividad
Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04251E
Reference62 articles.
1. Topologically Interesting Cages for Negative Ions with Extremely High“Coordination Number”: An Unusual Property of V-O Clusters
2. The preparation and crystal structure of a salt with the [{VO2(O2CMe)}4(NO3)] monoanion
3. The cyclic vanadylacetate (C24H20P)[V4O8(C2H3O2)4(NO3)]
4. Investigations of the vanadium–oxo–organophosphonato system: preparation and structural characterization of a mixed-valence VV–VIVcluster encapsulating chloride anions, (Bu4N)2[(V8O16){V4O4(H2O)12}(PhPO3)8Cl2]·2Et2O·2MeOH·4H2O
5. Synthesis of tetranuclear and pentanuclear vanadium-oxide-carboxylate aggregates
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