The selectivity of diglycolamide (TODGA) and bis-triazine-bipyridine (BTBP) ligands in actinide/lanthanide complexation and solvent extraction separation – a theoretical approach-Reference-Cited by-同舟云学术

The selectivity of diglycolamide (TODGA) and bis-triazine-bipyridine (BTBP) ligands in actinide/lanthanide complexation and solvent extraction separation – a theoretical approach

Published:2015 Issue:6 Volume:44 Page:2657-2666
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Narbutt Jerzy¹²³,Wodyński Artur¹²³⁴⁵,Pecul Magdalena⁴⁵⁶³

Affiliation:

1. Institute of Nuclear Chemistry and Technology

2. 03-195 Warsaw

3. Poland

4. University of Warsaw

5. Faculty of Chemistry

6. 02-093 Warsaw

Abstract

Charge transfer from the ligand to valence hybrid (mainly d) metal orbitals nearly equally stabilizes cationic Eu^III and Am^III TODGA complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02657H

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4. Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N-Donor Ligands

5. Use of Soft Heterocyclic N-Donor Ligands To Separate Actinides and Lanthanides

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