Structure and molecular mobility of phosphinine-based covalent organic frameworks – glass transition of amorphous COFs

Author:

Emamverdi Farnaz1,Huang Jieyang2ORCID,Szymoniak Paulina1,Bojdys Michael J.2,Böhning Martin1ORCID,Schönhals Andreas1ORCID

Affiliation:

1. Bundesanstalt für Materialforschung und -prüfung (BAM), Unter den Eichen 87, Berlin 12205, Germany

2. Department of Chemistry, Humboldt University, Brook-Taylor Straße 2, Berlin 12489, Germany

Abstract

Two-dimensional covalent organic frameworks (COFs) based on phosphinine and thiophene building blocks have been synthesized with two different side groups and investigated by complementary methods.

Publisher

Royal Society of Chemistry (RSC)

Reference66 articles.

1. Covalent organic frameworks (COFs): from design to applications

2. N. G.McCrum ; C. P.Buckley and C. B.Bucknall , Principles of polymer engineering , Oxford University Press , New York , 1997

3. Sawhorse connections in a Ag(I)-nitrite coordination network: {[Ag(pyrazine)]NO2}∞

4. Nanoporous organic polymer networks

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