The effects of halogen bonding and molecular design on the self-assembly of coordination polymers of Mn(iii)-tetraarylporphyrin with axial bridging ligands
Author:
Affiliation:
1. School of Chemistry
2. Sackler Faculty of Exact Sciences
3. Tel-Aviv University
4. 6997801 Tel-Aviv, Israel
Abstract
Two new coordination polymers of Mn(iii)-tetra(iodophenyl)porphyrin with isonicotinate and pyrimidine-5-carboxylate linkers have been synthesized. The effect of halogen-bonding interactions on their self-assembly in the crystalline bulk and on a graphite surface has been discussed.
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CE/C4CE01125B
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