Possible B–C bonding in the hydroboration of benzonitrile by an external electric field-Reference-Cited by-同舟云学术

Possible B–C bonding in the hydroboration of benzonitrile by an external electric field

Published:2019 Issue:1 Volume:21 Page:18-21
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zhang Ming-Xia¹²³⁴⁵,Xu Hong-Liang¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Functional Material Chemistry

2. Department of Chemistry

3. National & Local United Engineering Laboratory for Power Battery

4. Northeast Normal University

5. Changchun 130024

Abstract

Generally, the hydroboration of benzonitrile produces B–N containing compound. An unprecedented B–C bond may be formed in the presence of suitable external electric field (EEF), which could influence hydroboration and control selectivity by changing its magnitude and directions.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06704J

Reference51 articles.

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2. H. C. Brown , Boranes in Organic Chemistry , Cornell University Press , Ithaca , 1972