Effect of ligand denticity on the nitric oxide reactivity of cobalt(ii) complexes-Reference-Cited by-同舟云学术

Effect of ligand denticity on the nitric oxide reactivity of cobalt(ii) complexes

Published:2016 Issue:27 Volume:45 Page:10979-10988
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Deka Hemanta¹²³⁴,Ghosh Somnath¹²³⁴,Saha Soumen¹²³⁴,Gogoi Kuldeep¹²³⁴,Mondal Biplab¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Guwahati

3. Assam-781039

4. India

Abstract

NO reactivity of three Co(ii) complexes, 1, 2 and 3 have been studied in degassed methanol solution. The complexes differ from each other in terms of denticity and flexibility of the ligand fameworks. Complex 1 undergoes reductive nitrosylation of the metal ion; 2 results in corresponding [Co^III(NO⁻)] complex; whereas 3 does not react with NO.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01169A

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