Synthesis of a tethered dibenzotetramethyltetraaza[14]annulene macrocycle and the di-nickel(ii) derivative

Author:

Dey Soumyajit12345,Dewey Jacob R.12345,Wayland Bradford B.12345,Zdilla Michael J.12345ORCID

Affiliation:

1. Department of Chemistry

2. Temple University

3. 1901 N. 13th Street

4. Philadelphia

5. USA

Abstract

Selective reaction of 2,6-isophthaloyl chloride at the methine positions of two dibenzotetramethyltetraaza[14]annulene (tmtaa) units results in tethering of the macrocycles by either one or two 2,6-isophthaloyl bridging groups.

Funder

Division of Chemistry

Pennsylvania Department of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference39 articles.

1. M. Beller and C.Bolm , Transition Metals for Organic Synthesis , Wiley-VCH , Weinheim, Germany , 2004 , vol. 2

2. F. Diederich , P. J.Stang and R. R.Tykwinski , Acetylene Chemistry: Chemistry, Biology and Material Science , Wiley-VCH , Weinheim, Germany , 2005

3. B. M. Trost and C.-J.Li , Modern Alkyne Chemistry: Catalytic and Atom-Economic Transformation , Wiley-VCH , Weinheim, Germany , 2015

4. One-flask synthesis of dibenzotetraaza[14]annulene cyclic congeners bearing buta-1,3-diyne bridges

5. Synthesis, characterization, and preceramic properties of π-conjugated polymers based on Ni(II) complexes of goedken's macrocycle

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