The effects of protonated heterocyclic cations on the structural and magnetic properties of tetrachlorocuprate(ii) anions; X-ray, magnetochemical and EPR studies-Reference-Cited by-同舟云学术

The effects of protonated heterocyclic cations on the structural and magnetic properties of tetrachlorocuprate(ii) anions; X-ray, magnetochemical and EPR studies

Published:2018 Issue:19 Volume:42 Page:15705-15713
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kersen Ülo¹²³⁴,Wojtczak Andrzej⁵⁶⁷⁸⁹,Bienko Alina⁶¹⁰¹¹⁹^ORCID,Jezierska Julia⁶¹⁰¹¹⁹

Affiliation:

1. School of Chemical Engineering

2. Aalto University

3. 00076 Aalto

4. Finland

5. Department of Crystallochemistry and Biocrystallography

6. Faculty of Chemistry

7. Nicolaus Copernicus University

8. 87-100 Torun

9. Poland

10. University of Wroclaw

11. 50-383 Wroclaw

Abstract

The crystal and molecular structures and magnetic properties of two new complexes (HMepy)₂[CuCl₄]·2H₂O, 2, and (H₂Me₂ppz)[CuCl₄], 3, formed by tetrachlorocuprate(ii) anions and organic heterocyclic cations, have been determined by the analysis of their X-ray diffraction data, magnetic susceptibility behaviour and EPR spectral parameters.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ03155J

Reference26 articles.

1. A new copper chloride chain by supported hydrogen bonding

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3. Structures of bis(4-aminopyridinium) tetrachlorocuprate(II) monohydrate, [C5H7N2]2[CuCl4].H2O and bis(2-amino-3-hydroxypyridinium) tetrachlorocuprate(II), [C5H7N2O]2[CuCl4]: correlation of CuCl4 2− geometry with hydrogen bonding and electronic structure

4. Tetrahalidocuprates(ii) – structure and EPR spectroscopy. Part 2: tetrachloridocuprates(ii)

5. Magnetic exchange interactions in tetrabromocuprate compounds

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