Acid-Catalyzed Oxidative Cross-Coupling of Acridans with Silyl Diazoenolates and Rh-Catalyzed Rearrangement: Two-step Synthesis of γ-(9-Acridanylidene)-β-keto Esters
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Published:2021
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Volume:
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ISSN:1477-0520
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Container-title:Organic & Biomolecular Chemistry
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language:en
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Short-container-title:Org. Biomol. Chem.
Author:
Li Wei-Yu,Xu Hao,Zhou Lei
Abstract
A MsOH-catalyzed oxidative cross-coupling of acridans and silyl diazoenolates and Rh2(OAc)4-catalyzed rearrangement of the resultant diazo products were described. The reactions provide various γ-(9-acridanylidene)-β-keto esters in good yields, which bear...
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry