Suppressing the active site-blocking impact of ligands of Ni6(SR)12 clusters with the assistance of NH3 on catalytic hydrogenation of nitriles-Reference-Cited by-同舟云学术

Suppressing the active site-blocking impact of ligands of Ni6(SR)12 clusters with the assistance of NH3 on catalytic hydrogenation of nitriles

Author:

Chai Xiaoqi¹²³⁴⁵,Li Tao⁶⁷⁸⁵^ORCID,Chen Mingyang⁹¹⁰⁵^ORCID,Jin Rongchao¹¹¹²¹³¹⁴,Ding Weiping¹²³⁴⁵^ORCID,Zhu Yan¹²³⁴⁵^ORCID

Affiliation:

1. Key Lab of Mesoscopic Chemistry

2. School of Chemistry and Chemical Engineering

3. Nanjing University

4. Nanjing 210093

5. P.R. China

6. School of Physical Science and Technology

7. Shanghai Tech University

8. Shanghai 201210

9. Beijing Computational Science Research Center

10. Beijing 100193

11. Department of Chemistry

12. Carnegie Mellon University

13. Pittsburgh

14. USA

Abstract

The activity of Ni₆(SR)₁₂ for nitriles hydrogenation is enhanced with the assistance of NH₃ that suppresses the ligand shielding effect.

Funder

Nanjing University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

Reference34 articles.

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