Sniffing out camphor: the fine balance between hydrogen bonding and London dispersion in the chirality recognition with α-fenchol-Reference-Cited by-同舟云学术

Sniffing out camphor: the fine balance between hydrogen bonding and London dispersion in the chirality recognition with α-fenchol

Published:2022 Issue:21 Volume:24 Page:12849-12859
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Quesada-Moreno María Mar¹²^ORCID,Fatima Mariyam¹³^ORCID,Medel Robert⁴^ORCID,Pérez Cristóbal¹⁵^ORCID,Schnell Melanie¹⁶^ORCID

Affiliation:

1. Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany

2. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Avda. Fuentenueva s/n, 18071, Granada, Spain

3. I. Institute of Physics, Universität zu Köln, Zülpicher Straße 77, 50937 Köln, Germany

4. Institut für Physikalische Chemie, Universität Göttingen, Tammannstr. 6, D-37077 Göttingen, Germany

5. Departamento de Química Física y Química Inorgánica, Facultad de Ciencias & I.U. CINQUIMA, Universidad de Valladolid, E-47011 Valladolid, Spain

6. Christian-Albrechts-Universität zu Kiel, Institut für Physikalische Chemie, Max-Eyth-Straße 1, 24118 Kiel, Germany

Abstract

Complexes between the chiral monoterpenoids camphor and α-fenchol were explored with vibrational and rotational jet spectroscopy as well as density functional theory to explore how chirality can influence the binding preferences in the gas phase.

Funder

Deutsche Forschungsgemeinschaft

Ministerio de Ciencia, Innovación y Universidades

Fundación Alfonso Martín Escudero

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP00308B

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