Clavipines A–C, antiproliferative meroterpenoids with a fused azepine skeleton from the basidiomycete Clitocybe clavipes

Author:

Sun Zhaocui12345ORCID,Zhu Nailiang12345ORCID,Zhou Man678910,Huo Xiaowei1112131410,Wu Haifeng12345,Tian Yu12345ORCID,Yang Junshan12345,Ma Guoxu12345,Yang Yan-Long678910,Xu Xudong12345

Affiliation:

1. Key Laboratory of Bioactive Substances and Resource Utilization of Chinese Herbal Medicine

2. Ministry of Education

3. Institute of Medicinal Plant Development

4. Peking Union Medical College and Chinese Academy of Medical Sciences

5. Beijing 100193

6. State Key Laboratory of Applied Organic Chemistry

7. College of Chemistry and Chemical Engineering

8. Lanzhou University

9. Lanzhou 730000

10. People's Republic of China

11. College of Pharmaceutical Science

12. Key Laboratory of Pharmaceutical Quality Control of Hebei Province

13. Hebei University

14. Baoding 071002

Abstract

Three novel meroterpenoids, clavipines A–C (1–3), possessing a benzoquinone fused to an azepine ring and a ten-membered carbocycle with α,β-epoxy/unsaturated-γ-lactone, were isolated from the basidiomycete Clitocybe clavipes.

Funder

Chinese Academy of Medical Sciences

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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