Size and surface-energy dependence of the adsorption/desorption equilibrium in ethanol electro-oxidation by Pd-nanoparticles. Theory and experiment-Reference-Cited by-同舟云学术

Size and surface-energy dependence of the adsorption/desorption equilibrium in ethanol electro-oxidation by Pd-nanoparticles. Theory and experiment

Published:2022 Issue:4 Volume:12 Page:2525-2530
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Maya-Cornejo J.¹^ORCID,Hernández S. I.¹^ORCID,Estévez Miriam²,Santamaría-Holek I.¹^ORCID

Affiliation:

1. Unidad Multidisciplinaria de Docencia e Investigación-Juriquilla, Facultad de Ciencias, Universidad Nacional Autónoma de México, Juriquilla, Querétaro 76230, Mexico

2. Centro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, Boulevard Juriquilla 3001, 76230 Santiago de Querétaro, Qro, Mexico

Abstract

The current–voltage relation of ethanol electro-oxidation by Pd nanoparticles depends on their radius, the temperature and electron-transfer coefficient, the adsorption equilibrium constant, the surface energy, and the number of active surface sites.

Funder

Consejo Nacional de Ciencia y Tecnología

Universidad Nacional Autónoma de México

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D1RA08742H

Reference29 articles.

1. Efficient electrooxidation of methanol and ethanol using MoOx-decorated Pd catalysts in alkaline media

2. Methanol and ethanol electrooxidation on Pt and Pd supported on carbon microspheres in alkaline media

3. Monodispersed Pd nanospheres and their electrocatalytic properties for methanol oxidation in alkaline medium

4. Synthesis of Ni–Pd nanocubes and nanorods with high selectivity through a modified polyol process

5. Activation of specific sites on cubic nanocrystals: a new pathway for controlled epitaxial growth towards catalytic applications

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