Lithium metal atoms fill vacancies in the germanium network of a type-I clathrate: synthesis and structural characterization of Ba<sub>8</sub>Li<sub>5</sub>Ge<sub>41</sub>-Reference-Cited by-同舟云学术

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Lithium metal atoms fill vacancies in the germanium network of a type-I clathrate: synthesis and structural characterization of Ba₈Li₅Ge₄₁

Published:2023 Issue:30 Volume:52 Page:10310-10322
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ghosh Kowsik¹^ORCID,Ovchinnikov Alexander¹²^ORCID,Baitinger Michael³^ORCID,Krnel Mitja³^ORCID,Burkhardt Ulrich³,Grin Yuri³,Bobev Svilen¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA

2. Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany

3. Max Plank Institut für Chemische Physik fester Stoffe, 01187 Dresden, Germany

Abstract

New clathrate type phases where Li atoms fill vacancies in the Ge-framework have been identified.

Funder

Division of Materials Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01168B

Reference80 articles.

1. Clathrate Structure of Silicon Na 8 Si 46 and Na x Si 136 ( x < 11)

2. Clathrates of Group 14 with Alkali Metals: An Exploration

3. Superconductivity in germanium clathrateBa8Ga16Ge30

4. Superconductivity in the Silicon Clathrate Compound (Na,Ba)xSi46

5. Vibrational modes in silicon clathrate compounds: A key to understanding superconductivity

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1. Applicability of the Zintl Concept to Understanding the Crystal Chemistry of Lithium-Rich Germanides and Stannides;Inorganic Chemistry;2024-05-29

2. Single crystal synthesis and physical property of Ba8Cu1·0Ni2.5Ga10Si33.5 clathrate;Heliyon;2024-03

3. Ordering by cation replacement in the system Na_2−xLi_xGa₇;Dalton Transactions;2024

4. Results from Exploratory Work in Li-Rich Regions of the AE-Li-Ge Systems (AE = Ca, Sr, Ba);Crystals;2023-12-31

5. Synthesis and Crystal and Electronic Structures of the Zintl Phase Sr21Cd4Sb18;Solids;2023-11-17

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