Electrolyte solvation structure manipulation enables safe and stable aqueous sodium ion batteries

Author:

Ao Huaisheng12345,Chen Chunyuan67895,Hou Zhiguo12345,Cai Wenlong12345,Liu Mengke12345,Jin Yueang12345,Zhang Xin67895ORCID,Zhu Yongchun12345ORCID,Qian Yitai12345ORCID

Affiliation:

1. Department of Applied Chemistry

2. Hefei National Laboratory for Physical Science at Microscale

3. University of Science and Technology of China

4. Hefei

5. China

6. State Key Laboratory of Chemical Resource Engineering

7. Beijing Advanced Innovation Center for Soft Matter Science and Engineering

8. Beijing University of Chemical Technology

9. Beijing 100029

Abstract

A multi-component aqueous electrolyte with a composite solvent sheath can widen the voltage window to 2.8 V and inhibit side reactions. A solid electrolyte interface layer containing Na2CO3 and organic compounds suppresses the reaction of water with the discharged anode.

Funder

National Basic Research Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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