Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex-Reference-Cited by-同舟云学术

Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex

Published:2016 Issue:4 Volume:7 Page:2579-2586
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bézier David¹²³⁴,Guan Changjian⁵⁶⁷⁸⁴,Krogh-Jespersen Karsten⁵⁶⁷⁸⁴,Goldman Alan S.⁵⁶⁷⁸⁴,Brookhart Maurice¹²³⁴

Affiliation:

1. Department of Chemistry

2. The University of North Carolina at Chapel Hill

3. Chapel Hill

4. USA

5. Department of Chemistry and Chemical Biology

6. Rutgers

7. The State University of New Jersey

8. New Brunswick

Abstract

A rhodium complex based on the bis-phosphine carbazolide pincer ligand was investigated in the context of alkane dehydrogenation and in comparison with its iridium analogue.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04794C

Reference51 articles.

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2. M. Findlater , J.Choi, A.Goldman and M.Brookhart, in Alkane C–H Activation by Single-Site Metal Catalysis, ed. P. J. Pérez, Springer, Netherlands, 2012, vol. 38, ch. 4, p. 113

3. Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes

4. D. Morales-Morales , Iridium Complexes Org. Synth., 2009

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