Salt-promoted catalytic methanol carbonylation using iridium pincer-crown ether complexes-Reference-Cited by-同舟云学术

Salt-promoted catalytic methanol carbonylation using iridium pincer-crown ether complexes

Published:2018 Issue:12 Volume:8 Page:3133-3143
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Gregor Lauren C.¹²³⁴,Grajeda Javier¹²³⁴,White Peter S.¹²³⁴,Vetter Andrew J.⁵⁶⁴,Miller Alexander J. M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of North Carolina at Chapel Hill

3. Chapel Hill

4. USA

5. Eastman Chemical Company

6. Kingsport

Abstract

Iridium complexes of pincer ligands containing aza-crown ether macrocycles are precatalysts for methanol carbonylation. Turnover numbers for all acetyl-containing products could be tuned from 265 to 1950 using metal and tetrabutylammonium salts.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00328A

Reference39 articles.

1. A. Haynes , in Comprehensive Inorganic Chemistry II , Elsevier, 2013 , pp. 1–24

2. Promotion of Iridium-Catalyzed Methanol Carbonylation: Mechanistic Studies of the Cativa Process

3. A. Haynes and S.Sheffield , in Catalytic Carbonylation Reactions. Topics in Organometallic Chemistry , ed. M. Beller , 2006 , vol. 18, pp. 179–205

4. High productivity methanol carbonylation catalysis using iridium

Cited by 23 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Homogeneous methanol carbonylation;Homogeneous Carbonylation and Hydroformylation Reactions;2024

2. CrownPhos: A Review of Crown Ether Derivatives Decorated with Phosphorus Donors;Comments on Inorganic Chemistry;2023-09-06

3. Tunable and Switchable Catalysis Enabled by Cation-Controlled Gating with Crown Ether Ligands;Accounts of Chemical Research;2023-03-28

4. Homogeneous Catalysis for the Conversion of CO₂, CO, CH₃OH, and CH₄ to C₂₊ Chemicals via C–C Bond Formation;ACS Catalysis;2023-03-13

5. Chemical Transformations in Heterobimetallic Complexes Facilitated by the Second Coordination Sphere;Modes of Cooperative Effects in Dinuclear Complexes;2023