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Influence of the solvent in the self-assembly and binding properties of [1 + 1] tetra-imine bis-calix[4]pyrrole cages

  • Published:2023 Issue:1 Volume:14 Page:186-195
  • ISSN:2041-6520
  • Container-title:Chemical Science
  • language:en
  • Short-container-title:Chem. Sci.

Author:

Mirabella Chiara F. M.12ORCID,Aragay Gemma1ORCID,Ballester Pablo13ORCID

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST), Avgda. Països Catalans, 16, 43007 Tarragona, Spain

2. Universitat Rovira i Virgili, Departament de Química Analítica i Química Orgànica, c/Marcel·lí Domingo,1, 43007 Tarragona, Spain

3. ICREA, Passeig Lluís Companys, 23, 08010 Barcelona, Spain

Abstract

We report the self-assembly and binding properties of [1+1] tetra-imine cages based on two different tetra-α aryl-extended calix[4]pyrrole scaffolds in chlorinated solvents and in a 9 : 1 CDCl3 : CD3CN solvent mixture.

Funder

Ministerio de Ciencia e Innovación

European Commission

Centres de Recerca de Catalunya

Generalitat de Catalunya

Agència de Gestió d'Ajuts Universitaris i de Recerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference48 articles.

1. Molecular Encapsulation

2. Container Molecules and Their Guests , ed. D. J. Cram and J. M. Cram , The Royal Society of Chemistry , Cambridge, England , 1997

3. Molecular cages for biological applications

4. Purely Covalent Molecular Cages and Containers for Guest Encapsulation

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