Titanium-mediated cross-coupling reactions of 1,3-butadiynes with α-iminonitriles to 3-aminopyrroles: observation of an imino aza-Nazarov cyclization
Author:
Affiliation:
1. State Key Laboratory of Organometallic Chemistry
2. Shanghai Institute of Organic Chemistry
3. Chinese Academy of Sciences
4. Shanghai 200032, People's Republic of China
Abstract
Ti(OiPr)4/2 nBuLi-mediated highly efficient cross-coupling reactions of 1,3-butadiynes with α-iminonitriles are described, which provide convenient access to functionalized 3-aminopyrroles.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/QO/C4QO00159A
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