Synthesis, characterization, DFT calculations, and reactivity study of a nitrido-bridged dimeric vanadium(iv) complex-Reference-Cited by-同舟云学术

Synthesis, characterization, DFT calculations, and reactivity study of a nitrido-bridged dimeric vanadium(iv) complex

Published:2020 Issue:4 Volume:49 Page:1200-1206
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lugosan Adriana¹²³⁴^ORCID,Cundari Thomas⁵⁶⁷⁸⁴,Fleming Kristin¹²³⁴,Dickie Diane A.⁵⁹¹⁰⁴^ORCID,Zeller Matthias⁵¹¹¹²⁴,Ghannam Jack¹²³⁴^ORCID,Lee Wei-Tsung¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Loyola University Chicago

3. Chicago

4. USA

5. Department of Chemistry

6. Center for Advanced Scientific Computing and Modeling (CASCaM)

7. University of North Texas

8. Denton

9. Brandeis University

10. Waltham

11. Purdue University

12. West Lafayette

Abstract

Synthesis and characterization of a rare nitrido-bridged vanadium(iv) dimer complex via both V^III–N₂ and V^III–N₃ activation by chemical reduction.

Funder

Loyola University Chicago

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04544A

Reference48 articles.

1. The Fe–V Cofactor of Vanadium Nitrogenase Contains an Interstitial Carbon Atom

2. The structure of vanadium nitrogenase reveals an unusual bridging ligand

3. The in vivo hydrocarbon formation by vanadium nitrogenase follows a secondary metabolic pathway

4. Vanadium Nitrogenase Reduces CO

5. Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

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