A neptunium(v)-mediated interwoven transuranium-rotaxane network incorporating a mechanically interlocked [c2]daisy chain unit

Author:

Mei Lei12345ORCID,Xu Chao67895,Wu Qun-yan12345ORCID,Hu Kong-qiu12345,Yuan Li-yong12345ORCID,Chen Jing67895,Xiao Cheng-liang10111213ORCID,Wang Shu-ao10111213ORCID,Chai Zhi-fang12345,Shi Wei-qun12345ORCID

Affiliation:

1. Laboratory of Nuclear Energy Chemistry

2. Institute of High Energy Physics

3. Chinese Academy of Sciences

4. Beijing 100049

5. China

6. Nuclear Chemistry and Chemical Engineering Division

7. Institute of Nuclear and New Energy Technology

8. Tsinghua University

9. Beijing 100084

10. School of Radiological & Interdisciplinary Sciences

11. Soochow University

12. Suzhou

13. P. R. China

Abstract

A combination of an NpV center and a cucurbituril-based pseudorotaxane ligand generates the first transuranium-rotaxane complex, NRCP-1, which has a mechanically-interlocked [c2]daisy chain unit.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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