Reactivity of oxidants towards phenyl and benzyl substituted 5-selanylpentanoic acids: radiolytic and theoretical insights

Author:

Singh Beena G.12ORCID,Prasanthkumar Kavanal P.3ORCID,Mangiavacchi Francesca45ORCID,Marini Francesca4ORCID,Santi Claudio4ORCID

Affiliation:

1. Radiation & Photochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai – 4000851, India

2. Homi Bhabha National Institute, Anushaktinagar, Mumbai – 400 094, India

3. Post Graduate and Research Department of Chemistry, Maharaja's College, Ernakulam, Kerala 682011, India

4. Group of Catalysis, Synthesis and Organic Green Chemistry, Department of Pharmaceutical Sciences, University of Perugia, Via del Liceo 1, 06123 Perugia, Italy

5. Department of Chemistry “Ugo Schiff”, University of Florence, Via della Lastruccia 13, Sesto Fiorentino, I-50019 Florence, Italy

Abstract

Two selanyl compounds, 5-(phenylselanyl)pentanoic acid (1) and 5-(benzylselanyl)pentanoic acid (2), were investigated for their reactivity towards one-electron oxidants. Compound 2 was found to possess better antioxidant properties than compound 1.

Funder

Dipartimenti di Eccellenza

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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