Dynamic lanthanide exchange between quadruple-stranded cages: the effect of ionic radius differences on kinetics and thermodynamics-Reference-Cited by-同舟云学术

Dynamic lanthanide exchange between quadruple-stranded cages: the effect of ionic radius differences on kinetics and thermodynamics

Published:2022 Issue:17 Volume:9 Page:4495-4505
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Rancan Marzio¹^ORCID,Rando Maria²^ORCID,Bosi Luigi²,Carlotto Alice²^ORCID,Seraglia Roberta³^ORCID,Tessarolo Jacopo⁴^ORCID,Carlotto Silvia¹²^ORCID,Clever Guido H.⁴^ORCID,Armelao Lidia²⁵^ORCID

Affiliation:

1. Institute of Condensed Matter Chemistry and Technologies for Energy (ICMATE), National Research Council (CNR), c/o Department of Chemical Sciences, University of Padova, via F. Marzolo 1, 35131 Padova, Italy

2. Department of Chemical Sciences, University of Padova, via F. Marzolo 1, 35131 Padova, Italy

3. Institute of Condensed Matter and Technologies for Energy (ICMATE), National Research Council (CNR), Corso Stati Uniti, 4, 35127 Padova, Italy

4. Department of Chemistry and Chemical Biology, TU Dortmund University, 44227 Dortmund, Germany

5. Department of Chemical Sciences and Materials Technologies (DSCTM), National Research Council (CNR), Piazzale A. Moro 7, 00185 Roma, Italy

Abstract

[Ln2L4]2− helicates easily undergo transmetalation. The lanthanide ionic radius difference (ΔEIR) strongly affects the kinetics of the dynamic process while the thermodynamics is independent and mainly entropy driven.

Funder

Consiglio Nazionale delle Ricerche

Università degli Studi di Padova

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00641C

Reference65 articles.

1. Discriminating between lanthanide ions: self-assembly of heterodimetallic triple-stranded helicates