Exchange couplings and quantum phases in two dissimilar arrays of similar copper dinuclear units

Author:

Sartoris Rosana P.12345ORCID,Santana Vinicius T.6789ORCID,Freire Eleonora101112135,Baggio Ricardo F.101112135,Nascimento Otaciro R.1415161718ORCID,Calvo Rafael12345ORCID

Affiliation:

1. Departamento de Física

2. Facultad de Bioquímica y Ciencias Biológicas

3. Universidad Nacional del Litoral

4. Santa Fe

5. Argentina

6. CEITEC - Central European Institute of Technology

7. Brno University of Technology

8. Brno

9. Czech Republic

10. Gerencia de Investigación y Aplicaciones

11. Centro Atómico Constituyentes

12. Comisión Nacional de Energía Atómica

13. Buenos Aires

14. Departamento de Física e Ciencias Interdisciplinares

15. Instituto de Física de São Carlos

16. Universidade de São Paulo - USP

17. São Carlos

18. Brazil

Abstract

X-ray structure and EPR spectra of two dinuclear copper compounds allow us to study spin entanglement and quantum phase transitions. Their different 3D arrays and interdinuclear exchange paths produce important effects.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

European Social Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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