The catalytic effects of a thiazolium salt in the oxa-Diels–Alder reaction between benzaldehyde and Danishefsky's diene: a molecular electron density theory study-Reference-Cited by-同舟云学术

The catalytic effects of a thiazolium salt in the oxa-Diels–Alder reaction between benzaldehyde and Danishefsky's diene: a molecular electron density theory study

Published:2021 Issue:42 Volume:19 Page:9306-9317
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ríos-Gutiérrez Mar¹,Pérez Patricia²,Domingo Luis R.¹^ORCID,Soto-Delgado Jorge³^ORCID

Affiliation:

1. Departamento de Química Orgánica, Universidad de Valencia, Burjassot, Valencia, Spain

2. Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Universidad Andres Bello, Santiago, Chile

3. Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Universidad Andres Bello, Viña del Mar, Chile

Abstract

The oxa-Diels–Alder reaction in the presence of a [thiazolium] salt (a liquid ionic type), has been studied using Molecular Electron Density Theory. The acceleration found in the reaction comes from an increase of the global electron density transfer from HB formation.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Fondo Nacional de Desarrollo Científico y Tecnológico

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01415C

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