Atmospheric chemistry of CF3(CX2)2CH2OH: rate coefficients and temperature dependence of reactions with chlorine atoms and the subsequent pathways of alkyl and alkoxy radicals (X = H, F)-Reference-Cited by-同舟云学术

Atmospheric chemistry of CF3(CX2)2CH2OH: rate coefficients and temperature dependence of reactions with chlorine atoms and the subsequent pathways of alkyl and alkoxy radicals (X = H, F)

Published:2016 Issue:68 Volume:6 Page:63954-63964
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Bai Feng-Yang¹²³⁴⁵,Liu You-Jun⁶⁷⁸⁵,Wang Xu¹²³⁴⁵,Sun Yan-Qiu¹²³⁴⁵,Pan Xiu-Mei¹²³⁴⁵

Affiliation:

1. Institute of Functional Material Chemistry

2. Faculty of Chemistry

3. Northeast Normal University

4. 130024 Changchun

5. People’s Republic of China

6. Faculty of Physics

7. Aviation University of Air Force

8. 130022 Changchun

Abstract

The atmospheric and kinetic properties of CF₃(CX₂)₂CH₂OH (X = H, F) with chlorine atoms were studied by density functional and canonical variational transition state theories in conjunction with the small-curvature tunneling correction.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA10840G

Reference48 articles.

1. Atmospheric Chemistry of Oxygenated Volatile Organic Compounds: Impacts on Air Quality and Climate

2. Rate coefficients for the OH + CFH2CH2OH reaction between 238 and 355 K

3. Atmospheric gas-phase degradation and global warming potentials of 2-fluoroethanol, 2,2-difluoroethanol, and 2,2,2-trifluoroethanol