A reduced electrophilicity for simple Lewis acids A involved in non-covalent interactions with Lewis bases B-Reference-Cited by-同舟云学术

A reduced electrophilicity for simple Lewis acids A involved in non-covalent interactions with Lewis bases B

Published:2022 Issue:11 Volume:24 Page:6856-6865
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Alkorta Ibon¹^ORCID,Legon Anthony²^ORCID

Affiliation:

1. Instituto de Química Médica (IQM-CSIC), Juan de la Cierva, 3, E-28006 Madrid, Spain

2. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK

Abstract

Dissociation energies De for B⋯A = B +A can be written De = c′NBEA, where NB and EA are the nucleophilicities and electrophilicities of the Lewis base B and the Lewis acid A, respectively.

Funder

University of Bristol

Ministerio de Ciencia e Innovación

Comunidad de Madrid

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP00779G

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