Through bond and through space interactions in dehydro-diazine radicals: a case study of 3c-5e interactions

Author:

Saraswat Mayank1234,Venkataramani Sugumar1234ORCID

Affiliation:

1. Department of Chemical Sciences

2. Indian Institute of Science Education and Research (IISER) Mohali

3. Mohali

4. India

Abstract

Owing to the 3c-5e (3-centred-5-electrons) interactions between two nitrogen lone pairs and a radical electron, the dehydrodiazine radical isomers are very interesting from the fundamental point of view.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference80 articles.

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2. T. Eicher , S.Hauptmann and A.Speicher , The Chemistry of Heterocycles: Structures, Reactions, Synthesis and Applications , Wiley-VCH , New York , 3rd edn, 2012

3. The Practice of Medicinal Chemistry , ed. C. G. Wermuth , D. Aldous , P. Raboisson and D. Rognan , Elsvier, Academic Press , 4th edn, 2015

4. Kinetics of thermal decomposition of the diazines: shock-tube pyrolysis of pyrimidine

5. Dehydro-oxazole, thiazole and imidazole radicals: insights into the electronic structure, stability and reactivity aspects

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