Reactivity of hydropersulfides toward the hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer-Reference-Cited by-同舟云学术

Reactivity of hydropersulfides toward the hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer

Published:2018 Issue:7 Volume:20 Page:4793-4804
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Anglada Josep M.¹²³^ORCID,Crehuet Ramon¹²³^ORCID,Adhikari Sarju⁴⁵⁶⁷⁸^ORCID,Francisco Joseph S.⁴⁹⁸^ORCID,Xia Yu⁴⁵⁶⁷⁸^ORCID

Affiliation:

1. Institute of Advanced Chemistry of Catalonia IQAC-CSIC

2. Barcelona

3. Spain

4. Department of Chemistry

5. Purdue University

6. West Lafayette

7. Indiana

8. USA

9. University of Nebraska-Lincoln

Abstract

Hydropersulfides (RSSH) are highly reactive towards OH radical, and depending on the nature of R substitute, a selective OH substitution with S–S bond cleavage competes with the hydrogen abstraction by the radical.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Generalitat de Catalunya

Division of Chemistry

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP07570G

Reference60 articles.