Regioselectivity of concerted proton–electron transfer at the surface of a polyoxovanadate cluster-Reference-Cited by-同舟云学术

Regioselectivity of concerted proton–electron transfer at the surface of a polyoxovanadate cluster

Published:2023 Issue:6 Volume:14 Page:1386-1396
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Schreiber Eric¹^ORCID,Brennessel William W.¹^ORCID,Matson Ellen M.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Rochester, Rochester, NY, 14611, USA

Abstract

Introduction of a surface defect on a POV-alkoxide imparts both structural and electronic alterations, resulting in “switchable” PCET regiochemistry. Such features provide insight into PCET reactivity at metal oxide surfaces.

Funder

U.S. Department of Energy

University of Rochester

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05928B

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