Role of Lewis Acids in preventing the degradation of dithioester-dormant species in the RAFT polymerization of acrylamides in methanol to enable the successful dual control of molecular weight and tacticity-Reference-Cited by-同舟云学术

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Role of Lewis Acids in preventing the degradation of dithioester-dormant species in the RAFT polymerization of acrylamides in methanol to enable the successful dual control of molecular weight and tacticity

Published:2021 Issue:37 Volume:12 Page:5336-5341
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Imamura Yuji¹,Yamago Shigeru¹^ORCID

Affiliation:

1. Institute for Chemical Research, Kyoto University, Uji 611-0011, Japan

Abstract

Lewis acids suppressed degradation of dithiobenzoates in RAFT polymerization of acrylamides in methanol to enable control over molecular weight and dispersity along with enhanced stereoselectivity.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00683E

Reference31 articles.

1. Radical addition–fragmentation chemistry in polymer synthesis

2. Macromolecular design via reversible addition-fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization

3. Living Radical Polymerization by the RAFT Process – A Third Update

4. End-functional polymers, thiocarbonylthio group removal/transformation and reversible addition-fragmentation-chain transfer (RAFT) polymerization

5. Synthesis of Isotactic Poly(N-isopropylacrylamide) by RAFT Polymerization in the Presence of Lewis Acid

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