Construction of unsymmetrical heterobiaryls <i>via</i> the Cp*Rh(<scp>iii</scp>)-catalysed C–H/C–H coupling of heteroarenes-Reference-Cited by-同舟云学术

Construction of unsymmetrical heterobiaryls via the Cp*Rh(iii)-catalysed C–H/C–H coupling of heteroarenes

Published:2023 Issue:63 Volume:59 Page:9646-9649
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Parmar Diksha¹²,Sharma Tamanna¹,Sharma Akhilesh K.³^ORCID,Sharma Upendra¹²^ORCID

Affiliation:

1. C–H Activation & Phytochemistry Lab, Chemical Technology Division, CSIR-IHBT, Palampur 176061, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

3. Institute of Chemical Research of Catalonia (ICIQ-CERCA), The Barcelona Institute of Science and Technology, Av. Països Catalans, 16, Tarragona 43007, Spain

Abstract

Herein, a concise method for the Rh(iii)-catalyzed, directing-group-assisted C–H/C–H cross-coupling of N-heterocycles with other heteroarenes is disclosed for the synthesis of unsymmetrical heterobiaryl compounds in good to excellent yields.

Funder

Science and Engineering Research Board

Generalitat de Catalunya

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC03166G

Reference40 articles.

1. From Amino Acids to Heteroaromatics—Thiopeptide Antibiotics, Nature's Heterocyclic Peptides

2. Synthesis, Biological Evaluation, and Structure–Activity Relationships of a Novel Class of Apurinic/Apyrimidinic Endonuclease 1 Inhibitors

3. Oxidative C–H/C–H Coupling Reactions between Two (Hetero)arenes

4. Palladium-Catalyzed Oxidative CH/CH Cross-Coupling of Indoles and Pyrroles with Heteroarenes

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