Monitoring molecular vibronic coherences in a bichromophoric molecule by ultrafast X-ray spectroscopy

Author:

Keefer Daniel1234ORCID,Freixas Victor M.5678ORCID,Song Huajing910114ORCID,Tretiak Sergei910114ORCID,Fernandez-Alberti Sebastian5678ORCID,Mukamel Shaul1234ORCID

Affiliation:

1. Departments of Chemistry and Physics and Astronomy

2. University of California

3. Irvine

4. USA

5. Departamento de Ciencia y Tecnologia

6. Universidad Nacional de Quilmes/CONICET

7. Bernal

8. Argentina

9. Theoretical Division

10. Los Alamos National Laboratory

11. Los Alamos

Abstract

Coherences during the non-adiabatic dynamics of a bichromophoric molecules are probed via stimulated X-ray Raman signals. They survive for several hundred femtoseconds, despite highly heterogeneous contributions across the molecular sampling space.

Funder

Alexander von Humboldt-Stiftung

U.S. Department of Energy

Office of Science

Universidad Nacional de Quilmes

Agencia Nacional de Promoción Científica y Tecnológica

Consejo Nacional de Investigaciones Científicas y Técnicas

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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