Substitution at sp<sup>3</sup> boron of a six-membered NHC·BH<sub>3</sub>: convenient access to a dihydroxyborenium cation-Reference-Cited by-同舟云学术

Substitution at sp³ boron of a six-membered NHC·BH₃: convenient access to a dihydroxyborenium cation

Published:2022 Issue:23 Volume:58 Page:3783-3786
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kundu Gargi¹²,Ajithkumar V. S.¹²,Raj K. Vipin²³^ORCID,Vanka Kumar²³^ORCID,Tothadi Srinu²⁴^ORCID,Sen Sakya S.¹²^ORCID

Affiliation:

1. Inorganic Chemistry and Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411008, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

3. Physical and Material Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411008, India

4. Analytical and Environmental Sciences Division and Centralized Instrumentation Facility, CSIR-Central Salt and Marine Chemicals Research Institute, Gijubhai Badheka Marg, Bhavnagar-364002, India

Abstract

6-SIDipp·BH3 (1) was reacted with I2 to give corresponding iodoboranes (2 & 3), which underwent nucleophilic substitution reactions to furnish OTf and ONO2 substituted boranes (4–7). Treatment of Br2/H2O with 1 led to a dihydroxyborenium cation (8).

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC06816D

Reference26 articles.

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