Al(iii)-NTA-fluoride: a simple model system for Al–F binding with interesting thermodynamics-Reference-Cited by-同舟云学术

Al(iii)-NTA-fluoride: a simple model system for Al–F binding with interesting thermodynamics

Published:2020 Issue:39 Volume:49 Page:13726-13736
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hacaperková Eliška¹²³⁴⁵^ORCID,Jaroš Adam⁶⁷⁸⁵^ORCID,Kotek Jan¹²³⁴⁵^ORCID,Notni Johannes⁹¹⁰¹¹¹²^ORCID,Straka Michal⁶⁷⁸⁵,Kubíček Vojtěch¹²³⁴⁵^ORCID,Hermann Petr¹²³⁴⁵^ORCID

Affiliation:

1. Department of Inorganic Chemistry

2. Faculty of Science

3. Charles University

4. 128 40 Prague

5. Czech Republic

6. Institute of Organic Chemistry and Biochemistry

7. AS CR

8. 166 10 Prague

9. Institut für Pathologie und Pathologische Anatomie

10. Technische Universität München

11. 81675 München

12. Germany

Abstract

Unsaturated Al^III complex shows a fast exchange of water molecules, hydroxide and fluoride anions in the coordination sphere, highly pH-dependent fluoride binding and release of fluorides at high pH or at high phosphate anion concentrations.

Funder

European Regional Development Fund

Grantová Agentura, Univerzita Karlova

Grantová Agentura České Republiky

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02644A

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