Tuning of the antiferromagnetic-type interaction in photo-excited single-decker porphyrin–lanthanide complexes with different crown capping ligands-Reference-Cited by-同舟云学术

Tuning of the antiferromagnetic-type interaction in photo-excited single-decker porphyrin–lanthanide complexes with different crown capping ligands

Published:2024 Issue:2 Volume:53 Page:628-639
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Adi Langit Cahya¹^ORCID,Santria Anas¹²^ORCID,Ishikawa Naoto¹^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan

2. Research Center for Chemistry, National Research and Innovation Agency, Kawasan PUSPITEK, Serpong, Tangerang Selatan, Banten, 15314, Indonesia

Abstract

By using magnetic circular dichroism (MCD), antiferromagnetic-type J–L electronic interaction (ΔJL) in heteroleptic Dy–porphyrin complexes was successfully determined. The ΔJL was tuned by changing the coordinating atoms of the non-aromatic ligands.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT02842A

Reference45 articles.

1. Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level

2. Determination of Ligand-Field Parameters and f-Electronic Structures of Double-Decker Bis(phthalocyaninato)lanthanide Complexes

3. Simultaneous Determination of Ligand-Field Parameters of Isostructural Lanthanide Complexes by Multidimensional Optimization

4. Quantum Tunneling of Magnetization in Lanthanide Single-Molecule Magnets: Bis(phthalocyaninato)terbium and Bis(phthalocyaninato)dysprosium Anions

5. Single-Molecule Magnets