Metastable doubly threaded [3]rotaxanes with a large macrocycle-Reference-Cited by-同舟云学术

Metastable doubly threaded [3]rotaxanes with a large macrocycle

Published:2022 Issue:18 Volume:13 Page:5333-5344
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hertzog Jerald E.¹^ORCID,Maddi Vincent J.¹^ORCID,Hart Laura F.²^ORCID,Rawe Benjamin W.²^ORCID,Rauscher Phillip M.²^ORCID,Herbert Katie M.²³^ORCID,Bruckner Eric P.³^ORCID,de Pablo Juan J.²⁴^ORCID,Rowan Stuart J.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry, University of Chicago, Chicago, IL, 60637, USA

2. Pritzker School of Molecular Engineering, University of Chicago, Chicago, IL 60637, USA

3. Department of Macromolecular Science and Engineering, Case Western Reserve University, 2100 Adelbert Road, Cleveland, OH 44106, USA

4. Chemical Science and Engineering Division and Center for Molecular Engineering, Argonne National Laboratory, 9700 S. Cass Ave., Lemont, IL 60434, USA

Abstract

Multiple metastable doubly threaded [3]rotaxanes using a large 46 atom ring were prepared and fully characterized. Varying the stopper group size gave a range of interlocked stabilities in CDCl3 from a half-life of <1 minute to ca. 6 months.

Funder

Division of Chemistry

Division of Materials Research

National Science Foundation

University of Chicago

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01486F

Reference94 articles.