A DFT study of the role of water in the rhodium-catalyzed hydrogenation of acetone-Reference-Cited by-同舟云学术

A DFT study of the role of water in the rhodium-catalyzed hydrogenation of acetone

Published:2016 Issue:96 Volume:52 Page:13881-13884
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Polo Victor¹²³⁴,Schrock Richard R.⁵⁶⁷⁸,Oro Luis A.⁹¹⁰²³⁴

Affiliation:

1. Departamento de Química Física – Instituto de Biocomputación y Física de Sistemas complejos (BIFI) – Universidad de Zaragoza

2. Facultad de Ciencias 50009

3. Zaragoza

4. Spain

5. Department of Chemistry

6. Massachusetts Institute of Technology

7. Cambridge

8. USA

9. Universidad de Zaragoza – CSIC

10. Departamento de Química Inorgánica – Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

Abstract

Acetone hydrogenation by [RhH₂(PR₃)₂S₂]⁺ catalysts involves hydride migration to the ketone and subsequent reductive elimination assisted by two water molecules.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC07875C

Reference31 articles.

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3. The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives

4. Preparation and catalytic properties of some cationic iridium(III) and rhodium(III) dihydrido complexes

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