Ligand steric effects on α-diimine nickel catalyzed ethylene and 1-hexene polymerization
Author:
Affiliation:
1. Advanced Catalysis and Green Manufacturing Collaborative Innovation Center
2. School of Petrochemical Engineering
3. Changzhou University
4. Changzhou 213164
5. China
Abstract
α-Diimine nickel complexes with systematically varied ligand sterics were used as a precatalyst for ethylene and 1-hexene polymerizations. The catalytic activities, molecular weights and branching densities could be tuned over a very wide range.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA11783C
Reference71 articles.
1. Late-Metal Catalysts for Ethylene Homo- and Copolymerization
2. Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms
3. C2-Symmetric Ni(II) α-Diimines Featuring Cumyl-Derived Ligands: Synthesis of Improved Elastomeric Regioblock Polypropylenes
4. Multiple Insertion of a Silyl Vinyl Ether by (α-Diimine)PdMe+ Species
5. Cationic Polymerization and Insertion Chemistry in the Reactions of Vinyl Ethers with (α-Diimine)PdMe+ Species
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