Selective hydroformylation of alkyl acrylates using [2,2′-bis(dipyrrolylphosphinooxy)-1,1′-(±)-binaphthyl]/Rh catalyst: reversal of regioselectivity-Reference-Cited by-同舟云学术

Selective hydroformylation of alkyl acrylates using [2,2′-bis(dipyrrolylphosphinooxy)-1,1′-(±)-binaphthyl]/Rh catalyst: reversal of regioselectivity

Published:2017 Issue:24 Volume:7 Page:14816-14823
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Shu Xiao¹²³⁴⁵,Liang Haoran¹²³⁴⁵,Wu Qianhui¹²³⁴⁵,Zhou Fanding¹²³⁴⁵,Zheng Xueli¹²³⁴⁵^ORCID,Fu Haiyan¹²³⁴⁵,Xu Bin⁶⁷⁵,Li Ruixiang¹²³⁴⁵,Zhang Chunchun⁶⁷⁵,Chen Hua¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Green Chemistry and Technology of Ministry of Education

2. College of Chemistry

3. Sichuan University

4. Chengdu 610064

5. P. R. China

6. Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education

7. Zigong 643000

Abstract

Deuterioformylation clarified the possible mechanism for the regioselectivity reversal of hydroformylation of alkyl acrylate at low and high temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA01649B

Reference32 articles.

1. Rhodium/bisphosphite catalytic system for hydroformylation of styrene and its derivatives

2. Rh-catalyzed linear hydroformylation of styrene

3. Highly efficient catalytic system for the formation of dialdehydes from dicyclopentadiene hydroformylation

4. Rhodium-Mediated Asymmetric Hydroformylation with a Novel Bis(diazaphospholidine) Ligand

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