Reactive phenolic solvents applied to the synthesis of renewable aromatic polyesters with high isosorbide content

Author:

Bottega Pergher Bruno1,Girigan Narcisa1,Vlasblom Sietse1,Weinland Daniel H.1,Wang Bing2,van Putten Robert-Jan12,Gruter Gert-Jan M.12ORCID

Affiliation:

1. Van't Hoff Institute of Molecular Sciences, University of Amsterdam, P.O. Box 94720, 1090GS Amsterdam, The Netherlands

2. Avantium Chemicals BV, Zekeringstraat 29, 1014BV Amsterdam, The Netherlands

Abstract

Reactive phenolic solvents like p-cresol can be used to produce high MW polyesters (30–40 kDa) with high isosorbide content (50%). Aromatic polyesters like PICT can be made within very short polycondensation times (1–2 h).

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference31 articles.

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