Influence of the first and second coordination spheres on the diverse phenoxazinone synthase activity of cobalt complexes derived from a tetradentate Schiff base ligand

Author:

Panja Anangamohan1234ORCID,Jana Narayan Ch.1234,Brandão Paula56789

Affiliation:

1. Postgraduate Department of Chemistry

2. Panskura Banamali College

3. Panskura RS

4. India

5. Department of Chemistry

6. CICECO-Aveiro Institute of Materials

7. University of Aveiro

8. 3810-193 Aveiro

9. Portugal

Abstract

Cobalt complexes as functional models for phenoxazinone synthase showing the influence of both first and second order coordination spheres on the catalytic activity and important intermediates in the ESI mass spectrum providing better information on the mechanistic pathway.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference55 articles.

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2. Diastereospecific and Diastereoselective Syntheses of Ruthenium(II) Complexes Using N,N‘ Bidentate Ligands Aryl-pyridin-2-ylmethyl-amine ArNH-CH2-2-C5H4N and Their Oxidation to Imine Ligands

3. Dioxygenases in Catalysis by Metal Complexes, Oxygenases and Model Systems, ed. T. Funabiki, Kluwer Academic, Dordrecht, 1997, p. 19

4. Dioxygen Reactions in Bioinorganic Chemistry, ed. I. Bertini, H. B. Gray, S. J. Lippard and J. S. Valentine, University Science Books, Sausalito, 1994, p. 253

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