Four-coordinate Co(ii) and Fe(ii) complexes with bis(N-heterocyclic carbene)borate and their magnetic properties

Author:

Liu Yuan-Zhong12345,Wang Jing12345,Zhao Yue12345,Chen Lei12345,Chen Xue-Tai12345,Xue Zi-Ling6789

Affiliation:

1. State Key Laboratory of Coordination Chemistry

2. Nanjing National Laboratory of Microstructures

3. School of Chemistry and Chemical Engineering

4. Nanjing University

5. Nanjing 210093

6. Department of Chemistry

7. University of Tennessee

8. Knoxville

9. USA

Abstract

Both square planar and tetrahedral isomers of the four-coordinate Co(ii) complex with a bis(N-heterocyclic carbene)borate ligand were isolated while only a tetrahedral configuration was found for the Fe(ii) analogue.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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