Selective alkane hydroxylation and alkene epoxidation using H<sub>2</sub>O<sub>2</sub> and Fe(<scp>ii</scp>) catalysts electrostatically attached to a fluorinated surface-Reference-Cited by-同舟云学术

Selective alkane hydroxylation and alkene epoxidation using H₂O₂ and Fe(ii) catalysts electrostatically attached to a fluorinated surface

Published:2023 Issue:22 Volume:59 Page:3265-3268
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fujisaki Hiroto¹,Okamura Masaya²^ORCID,Hikichi Shiro²³^ORCID,Kojima Takahiko¹³^ORCID

Affiliation:

1. Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan

2. Department of Material and Life Chemistry, Kanagawa University, 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama, Kanagawa 221-8686, Japan

3. CREST, Japan Science and Technology Agency (JST), Japan

Abstract

Fe(ii) complexes with pentadentate ligands, including N-heterocyclic carbene moieties, were prepared and electrostatically attached onto the perfluorinated surface of a mesoporous aluminosilicate.

Funder

Japan Society for the Promotion of Science

Core Research for Evolutional Science and Technology

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC06998A

Reference38 articles.

1. Bioinspired Nonheme Iron Catalysts for C–H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants

2. A Predictably Selective Aliphatic C–H Oxidation Reaction for Complex Molecule Synthesis

3. Metal-Catalyzed Epoxidations of Alkenes with Hydrogen Peroxide

4. Efficient Epoxidation of Olefins with ≥99% Selectivity and Use of Hydrogen Peroxide

5. A "Green" Route to Adipic Acid: Direct Oxidation of Cyclohexenes with 30 Percent Hydrogen Peroxide

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