Scandium-catalyzed electrophilic alkene difunctionalization: regioselective synthesis of thiosulfone derivatives
Author:
Affiliation:
1. Key Lab of Colloid and Interface Chemistry of Ministry of Education
2. School of Chemistry and Chemical Engineering
3. Shandong University
4. Jinan
5. Shandong 250100
Abstract
A scandium(iii)-catalyzed electrophilic alkene difunctionalization reaction with the synergistic formation of two C–S bonds has been developed. This reaction features a broad substrate scope, simple procedures, 100% atom economy, and a reversed regioselectivity compared to previously studied alkene sulfonylation methods.
Funder
National Natural Science Foundation of China
Shandong University
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00138G
Reference41 articles.
1. Enzymatic Carbon–Sulfur Bond Formation in Natural Product Biosynthesis
2. Chiral Sulfur Ligands for Asymmetric Catalysis
3. Sulfur Containing Scaffolds in Drugs: Synthesis and Application in Medicinal Chemistry
4. Organocatalytic Carbon–Sulfur Bond-Forming Reactions
Cited by 54 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Synthesis of thiosulfonates through aerobic oxidation of thiophenol under metal-free conditions;Journal of Molecular Structure;2024-10
2. Bifunctionalization of α-Bromophenone: An Access to Functionalized β-Keto Thiosulfones;The Journal of Organic Chemistry;2024-09-12
3. Copper-Catalyzed Vicinal Thiocyanosulfonylation of Alkenes and Alkynes;The Journal of Organic Chemistry;2024-07-31
4. Selenosulfones, a Meetup of Chalcogens: A Journey Into Their Recent Chemistry;European Journal of Organic Chemistry;2024-06-05
5. The Difunctionalization of Alkenes Completed by DMTSM and CF3SO2Na without Metal Catalysts;Synlett;2024-03-07
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3