Elucidating the chemiexcitation of dioxetanones by replacing the peroxide bond with S–S, N–N and C

Elucidating the chemiexcitation of dioxetanones by replacing the peroxide bond with S–S, N–N and C–C bonds

Published:2021 Issue:39 Volume:45 Page:18518-18527
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Magalhães Carla M.¹,González-Berdullas Patricia¹^ORCID,Esteves da Silva Joaquim C. G.¹²^ORCID,Pinto da Silva Luís¹²^ORCID

Affiliation:

1. Chemistry Research Unit (CIQUP), Faculty of Sciences of University of Porto (FCUP), Rua do Campo Alegre 697, 4169-007, Porto, Portugal

2. LACOMEPHI, GreenUPorto, Faculty of Sciences of University of Porto (FCUP), Rua do Campo Alegre 697, 4169-007, Porto, Portugal

Abstract

Replacing the peroxide bond of dioxetanone prevents chemiluminescence by making its thermolysis energetically unfavorable and without a singlet chemiexcitation pathway.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ03440E

Reference59 articles.

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5. Quantum/molecular mechanics study of firefly bioluminescence on luciferase oxidative conformation

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