Switchable slow relaxation of magnetization in the native low temperature phase of a cooperative spin-crossover compound
Author:
Affiliation:
1. Instituto de Ciencia de Materiales de Aragón (ICMA)
2. CSIC and Universidad de Zaragoza
3. 50009 Zaragoza
4. Spain
Abstract
Field-induced slow relaxation of magnetization arising from local trigonal distortion at high-spin Fe(II) sites in [Fe(mtz)6](CF3SO3)2 is reversibly switched through light irradiation, the first example of native and switchable Single-Molecule-Magnet properties in a spin-crossover material.
Funder
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC04737H
Reference43 articles.
1. Molecular spintronics using single-molecule magnets
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5. Phthalocyanine-Based Magnets
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