Determination of the ion-conduction properties of Na<sub>3</sub>OBr and its dominant defect species-Reference-Cited by-同舟云学术

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Determination of the ion-conduction properties of Na₃OBr and its dominant defect species

Published:2023 Issue:46 Volume:11 Page:25734-25742
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Miyazaki Reona¹^ORCID,Ito Shiori¹,Ishigami Kana²,Miyazaki Hidetoshi¹,Hihara Takehiko¹

Affiliation:

1. Department of Physical Science and Engineering, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa, Nagoya 466-8555, Japan

2. Creative Engineering Program, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa, Nagoya 466-8555, Japan

Abstract

Na3OBr is fabricated using purified Na2O. The dominant lattice defects are the site mixing of Br− and O2− rather than the Schottky pairs. Conductivity of Na3OBr increases by doping excess Br− ions while Ca2+ doping results in the deterioration of the conductivity.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D3TA04318E

Reference39 articles.

1. Anti-perovskites for solid-state batteries: recent developments, current challenges and future prospects

2. Antiperovskite Electrolytes for Solid-State Batteries

3. Antiperovskite Superionic Conductors: A Critical Review

4. Superionic Conductivity in Lithium-Rich Anti-Perovskites

5. Room temperature synthesis of anti-perovskite structured Li2OHBr

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