Enantioselective oxygenation of exocyclic methylene groups by a manganese porphyrin catalyst with a chiral recognition site-Reference-Cited by-同舟云学术

Enantioselective oxygenation of exocyclic methylene groups by a manganese porphyrin catalyst with a chiral recognition site

Published:2020 Issue:8 Volume:11 Page:2121-2129
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Burg Finn¹²³⁴⁵^ORCID,Breitenlechner Stefan¹²³⁴⁵^ORCID,Jandl Christian¹²³⁴⁵,Bach Thorsten¹²³⁴⁵^ORCID

Affiliation:

1. Department Chemie

2. Catalysis Research Center (CRC)

3. Technische Universität München

4. 85747 Garching

5. Germany

Abstract

A Mn porphyrin complex with a remote hydrogen bonding motif induces a high enantioselectivity in the oxygenation of 3-alkylquinolones. Compared to an achiral Mn complex, the site-selectivity was completely altered in favour of less reactive methylene groups.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC06089H

Reference129 articles.

1. 3d Transition Metals for C–H Activation

2. Catalytic Enantioselective Transformations Involving C–H Bond Cleavage by Transition-Metal Complexes

3. Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities